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Courses taught 2009/2010:
CHE263 Organic Chemistry
CHE264 Organic Chemistry II
ENV101 Environmental Science |
EDUCATION
Ph.D. (2003), Chemistry, University of British Columbia
Dissertation: "Location, Disorder, and Dynamics of Guest Species in Zeolite Frameworks Studied by Solid State NMR and X-ray Diffraction."
B.Sc. Hons (1997), Chemistry, University of Guelph
B.C.S. (1997), Liberal Arts & Science, Redeemer University College
RESEARCH INTERESTS
- Solid-State Nuclear Magnetic Resonance Spectroscopy
- Structural Chemistry
- Materials Science
- Computational Chemistry
CURRENT RESEARCH
Understanding the atomic and molecular level structure of materials is of fundamental interest in chemistry and materials science. By understanding the structure of materials, a greater understanding of their functions can be developed. Nuclear magnetic resonance (NMR) spectroscopy, a close cousin to magnetic resonance imaging (MRI) that many are familiar with in a medical context, is a powerful tool for elucidating the structural features of materials. I am particular interested in exploring the ability of NMR spectroscopy to be used for crystallography – the determination of crystal structures – by which the atomic arrangement of materials can be determined.
RECENT PUBLICATIONS
S. Cadars, D.H. Brouwer, B.F. Chmelka. Probing local structures of siliceous zeolite frameworks by solid-state NMR and first-principles calculations of 29Si-O-29Si scalar couplings. Physical Chemistry Chemical Physics 2009, 11, 1825-1837.
D.H. Brouwer. Interplay between solid-state NMR and single-crystal X-ray diffraction. Encyclopedia of Magnetic Resonance 2008, online.
D.H. Brouwer. Crystal structure refinement with solid-state NMR: An improved structure of silica-ZSM-12 zeolite from 29Si chemical shift tensors. Journal of Magnetic Resonance 2008, 194, 136-146.
D.H. Brouwer, S. Alavi, J.A. Ripmeester. NMR crystallography of p-tert-butylcalix arene host-guest complexes using 1H complexation-induced chemical shifts. Physical Chemistry Chemical Physics 2008, 10, 3857-3860.
D.H. Brouwer. NMR crystallography of zeolites: Refinement of an NMR-solved crystal structure using ab initio calculations of 29Si chemical shift tensors. Journal of the American Chemical Society 2008, 130, 6306-6307.
D.H. Brouwer, G.D. Enright. Probing local structure in zeolite frameworks: Ultrahigh-field NMR measurements and accurate first principles calculations of zeolite 29Si magnetic shielding tensors. Journal of the American Chemical Society 2008, 130, 3095-3105.
C.A. Fyfe, D.H. Brouwer. Optimization, standardization, and testing of a new NMR method for the determination of zeolite host-organic guest crystal structures. Journal of the American Chemical Society 2006, 128, 11860-11871.
D.H. Brouwer, R.J. Darton, R.E. Morris, M.H. Levitt. A solid-state NMR method for solution of zeolite crystal structures. Journal of the American Chemical Society 2005, 127, 10365-10370.
D.H. Brouwer, P.E. Kristiansen, C.A. Fyfe, M.H. Levitt. Symmetry-based 29Si dipolar recoupling magic angle spinning NMR: A new method for investigating three-dimensional structures of zeolite frameworks. Journal of the American Chemical Society 2005, 127, 542-543.
PROFESSIONAL MEMBERSHIPS AND ASSOCIATIONS
Chemical Institute of Canada
PROFESSIONAL EXPERIENCE
NSERC Post-Doctoral Research Fellow (2003-2005) with Prof Malcolm Levitt, School of Chemistry, University of Southampton
Assistant Research Officer (2006-2008) Steacie Institute of Molecular Sciences, National Research Council of Canada